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Agriculture for Secondary Schools
                                                                Agriculture for Secondary Schools

            Since they are very small, they have a very large total surface area per unit volume
            on which chemical reactions can take place. Furthermore, clay and humus particles
            usually remain scattered and move over a large area in the soil solution. Clay and
            humus particles  are  therefore  called  soil  colloids.  Clay  colloids  are  also  called
            mineral colloids while humus colloids are called organic colloids. Soil colloids have

            two major chemical characteristics: They are negatively charged and exhibit ion
            exchange. Most chemical reactions in the soil occur on colloid surfaces because of
            their charged surfaces. Due to their chemical make-up and large surface area, they
            can attract ions (charged particles) within the soil solution.

            Ion exchange in soil

            Ions are atoms or groups of atoms, that is, molecules which have an electrical charge.
            The ions with positive (+) charge are termed as ‘cations’ while those with a negative
            (-) charge are called ‘anions’. Plants take up nutrients from the soil either as cations
            or anions. Many of the nutrient elements are cations. These include ammonium
            (NH ), calcium (Ca ), magnesium (Mg ), potassium (K ), iron (Fe ), manganese
                                                   2+
                                                                    +
                                2+
                                                                              3+
                 +
                 4
            (Mn ), zinc (Zn ) and copper (Cu ) ions. Other cations of importance are hydrogen
                            2+
                                             2+
                2+
            (H ) and aluminium (Al ). Cations are attracted to negatively charged surfaces of
               +
                                    3+
            clay and organic (humus) colloids. This attraction is called adsorption and the sites
            where cations attach to particles are cation-exchange sites.
            Cations can move from the adsorption sites on colloids into the soil solution and
            vice versa where they are available for root uptake and are also subject to leaching.
            Figure 2.1 (a)  shows the cation exchange in soil while Figure 2.1 (b) shows how
            plants obtain mineral nutrients from soil through cation exchange. Observing the
            figures, you can notice that cations dominate the exchange sites because the colloid is
            primarily negatively charged. You can also notice that cation exchange is important
            for maintaining adequate quantities of, among other cations found in the soil, plant-
            available calcium (Ca ), magnesium (Mg ) and potassium (K ). In addition, it can
                                                                        +
                                                     2+
                                 2+
            be noted in Figure 2.1 (b) that hydrogen ions (H ) help to make nutrients available
                                                           +
            by displacing the cations.













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   AGRICULTURE FORM 3   9.11.2022.indd   33                                               10/01/2025   12:31
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