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Chemistry
                                                                           for Secondary Schools



              Action of heat on salts
              Different salts behave differently when heated. Some salts will decompose after
              slight heating, yet others have to be heated strongly to decompose. Some salts do
              not decompose at all, even with strong heating.
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              Action of heat on carbonates

              Upon heating, metal carbonates decompose to form metal oxides and carbon
              dioxide gas. The decomposition reaction can be represented by the following
              equation, where M represents a particular metal:




              Sodium and potassium carbonates do not decompose even when strongly heated.
              The carbonates of magnesium and calcium decompose to give magnesium oxide
              and calcium oxide, respectively, with the evolution of carbon dioxide gas.







              Other  metal  carbonates  decompose  easily  on heating.  For example,  green
              copper(II) carbonate decomposes easily upon heating to give black copper(II)
              oxide and carbon dioxide gas.




              Zinc carbonate decomposes  easily on  heating to form zinc oxide and  carbon
              dioxide gas. The zinc oxide produced is yellow when hot and white when cold.




              Lead(II) carbonate decomposes when heated to give lead(II) oxide and carbon
              dioxide gas.




              Ammonium carbonate behaves so differently when heated. It decomposes slowly
              at room temperature to produce ammonia gas, water, and carbon dioxide.




              A strong pungent smell is produced due to the presence of ammonia gas. The
              evolved gas turns limewater milky, indicating the presence of carbon dioxide. It
              also turns a blue cobalt(II) chloride paper pink indicating the presence of water



                Student’s Book Form Two                                             133




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